WebFeb 9, 2024 · The stepwise catalytic reduction of carbon dioxide (CO 2) to formic acid, formaldehyde, and methanol opens non-fossil pathways to important platform chemicals.The present article aims at identifying molecular control parameters to steer the selectivity to the three distinct reduction levels using organometallic catalysts of earth-abundant first-row … WebIntroduction The oxidation of silanes to silanols is an important reaction due to the wide range of fields in which these products can be applied, including material sciences 1 and medicinal chemistry, 2 as well as in synthetic chemistry as directing groups, 3 organocatalysts 4 or cross-coupling partners. 5 Silanols are traditionally prepared by …
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WebJul 24, 2024 · Anthracene-bridged dinuclear rhenium complexes are reported for electrocatalytic carbon dioxide (CO2) reduction to carbon monoxide (CO). Related by hindered rotation of each rhenium active site to either side of the anthracene bridge, cis and trans conformers have been isolated and characterized. Electrochemical studies reveal … WebApr 20, 2024 · Niklas W. Kinzel, Christophe Werlé, Walter Leitner. Transition Metal Complexes as Catalysts for the Electroconversion of CO 2 : An Organometallic Perspective. Angewandte Chemie International Edition 2024, 60 (21) , 11628-11686. the tunnel club nairobi
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WebJan 13, 2024 · The catalytic hydrogenation activity of the readily prepared, coordinatively saturated cobalt(I) precatalyst, (R,R)-(iPrDuPhos)Co(CO)2H ((R,R)-iPrDuPhos = (+)-1,2-bis[(2R,5R)-2,5-diisopropylphospholano]benzene), is described. While efficient turnover was observed with a range of alkenes upon heating to 100 °C, the catalytic performance of … WebAug 3, 2016 · Dr. Christophe Werlé. Max-Planck-Institut für Kohlenforschung, 45470 Mülheim/Ruhr, Germany. Search for more papers by this author WebE-mail: [email protected], [email protected]. b Institut für Technische und Makromolekulare Chemie (ITMC), RWTH Aachen University, Worringer Weg 2, Aachen, Germany Abstract. Manganese(I) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. … sewing sticky tape